洪桂彬老師的歷程檔案

期刊名稱	Lee, M. J.; L. H. Tsai; G. B. Hong and H. M. Lin, “Multiphase Coexistence for Aqueous Systems with Amyl Alcohol and Amyl Acetate,” Industrial and Engineering Chemistry Research, 41, 3247-3252 (2002).
資料日期	2002-06-03

[英文摘要] :
Phase equilibrium properties were measured with a newly designed apparatus for the mixtures of amyl alcohol + water, amyl acetate + water, and water + amyl alcohol + amyl acetate at vapor-liquid-liquid equilibrium (VLLE) conditions up to 393.15 K. The experimental data form
a basis to evaluate the reliability of VLLE calculations with the -ç-ç method. It is found that the mutual solubility data can be correlated accurately by the NRTL model with temperaturedependent parameters for the binary aqueous systems over a wide temperature range. The saturated vapor compositions can also be calculated satisfactorily by using a two-term virial equation with one adjustable binary interaction parameter. The model parameters determined from the binary VLLE data of amyl alcohol + water and amyl acetate + water and the binary
vapor-liquid equilibrium (VLE) data of amyl alcohol + amyl acetate are applicable to reproducing
VLLE properties for the ternary system of water + amyl alcohol + amyl acetate.