洪桂彬老師的歷程檔案

期刊名稱	Lin, H. M.; G. B. Hong and M. J. Lee, “Liquid-Liquid Equilibria of Ternary Mixtures of Water + Ethanol with 1-Hexanol, Butyl Propionate or Ethyl Caproate,” Journal of Chemical Engineering Data, 48, 587-590 (2003).
資料日期	2003-07-01

[英文摘要] :
Liquid-liquid equilibrium (LLE) data were measured for the ternary mixtures of water + ethanol +
1-hexanol, water + ethanol + butyl propionate, and water + ethanol + ethyl caproate at atmospheric
pressure over a temperature range of 283.15 K to 323.15 K. All three ternary systems exhibit type I
behavior of LLE. The area of the two-phase region decreases with increasing temperature for each ternary
system; its magnitude follows the order of the mixtures containing ethyl caproate > butyl propionate >
1-hexanol. The NRTL and the UNIQUAC models correlated the LLE data very well, except for the region
near the plait point. The NRTL model is generally better than the UNIQUAC model for representing the
LLE behavior for the three investigated systems.